THE ADDITION ELIMINATION MECHANISM IN THE PHOTONITRATION OF NAPHTHALENE BY TETRANITROMETHANE

被引：25

作者：

EBERSON, L

HARTSHORN, MP

RADNER, F

ROBINSON, WT

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

[2] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000566

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the isolation and kinetic studies of an adduct (cis-1,4-dihydro-1-nitro-4-trinitromethylnaphthalene) from the photolysis of naphthalene-tetranitromethane in dichloromethane or acetonitrile, it is shown that the route to nitro substitution products proceeds via addition-elimination, the latter step being either thermal or base-catalysed.

引用

页码：566 / 567

页数：2

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