JANUS MOLECULES - SYNTHESIS OF DOUBLE-HEADED HETEROCYCLES CONTAINING 2 IDENTICAL HYDROGEN-BONDING ARRAYS

被引：47

作者：

MARSH, A

NOLEN, EG

GARDINIER, KM

LEHN, JM

机构：

[1] UNIV LOUIS PASTEUR,INST BEL,CHIM SUPRAMOLEC LAB,F-67000 STRASBOURG,FRANCE

[2] COLGATE UNIV,DEPT CHEM,HAMILTON,NY 13346

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 03期

关键词：

DIAMINOPYRIMIDOQUINAZOLINEDIONE; DIAMINOPYRIDOISOQUINOLINEDIONE; CHAPMAN REARRANGEMENT; HYDROGEN BONDING; MOLECULAR RECOGNITION; SELF-ASSEMBLY;

D O I：

10.1016/0040-4039(94)85063-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of three heterocycles 1-3 presenting identical Paces containing a hydrogen bonding code for self-assembly is described. Pyrimidoquinazolinetetrone 1 and diaminopyrimidoquinazolinedione 2 were approached using a double Chapman rearrangement followed by closure to the double uracil-type structure 1. Diaminopyridoisoquinolinedione 3 was obtained in three steps from pyromellitic anhydride.

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页码：397 / 400

页数：4

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