ADDITION OF QUADRICYCLANE TO C-60 - EASY ACCESS TO FULLERENE DERIVATIVES BEARING A REACTIVE DOUBLE-BOND IN THE SIDE-CHAIN

被引：35

作者：

PRATO, M

MAGGINI, M

SCORRANO, G

LUCCHINI, V

机构：

[1] CNR,CTR MECCAN REAZ ORGAN,DIPARTIMENTO CHIM ORGAN,I-35131 PADUA,ITALY

[2] UNIV VENEZIA,DIPARTIMENTO SCI AMBIENTALI,I-30133 VENICE,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 14期

关键词：

D O I：

10.1021/jo00066a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of C60 with quadricyclane gives a stable 6,6 adduct which has been spectroscopically characterized. The double bond of the [2.2.1]bicycloheptene moiety reacts readily with electrophiles (e.g., PhSCl).

引用

页码：3613 / 3615

页数：3

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