DELATISINE, A NOVEL DITERPENOID ALKALOID FROM DELPHINIUM-ELATUM L

被引：12

作者：

ROSS, SA

JOSHI, BS

DESAI, HK

PELLETIER, SW

NEWTON, MG

ZHANG, XL

SNYDER, JK

机构：

[1] UNIV GEORGIA,INST NAT PROD RES,ATHENS,GA 30602

[2] UNIV GEORGIA,SCH CHEM SCI,ATHENS,GA 30602

[3] UNIV GEORGIA,SCH CHEM SCI,X-RAY DIFFRACT LAB,ATHENS,GA 30602

[4] BOSTON UNIV,DEPT CHEM,BOSTON,MA 02215

来源：

TETRAHEDRON | 1991年 / 47卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(01)91026-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemical investigation of the seeds of Delphinium elatum L. resulted in the isolation of a new diterpenoid alkaloid delatisine whose structure (1) was established by H-1 COSY, long range COSY, HETCOR, 2D nOe, fixed evolution HETCOR and selective INEPT nmr studies. The structure of the alkaloid was confirmed by an X-ray crystal structure determination.

引用

页码：9585 / 9598

页数：14

共 25 条

[1]

BANDO H, 1988, CHEM PHARM BULL, V36, P1604

[2]

BANDO H, 1987, HETEROCYCLES, V26, P2623

[3] STRUCTURE DETERMINATION AND SPECTRAL ASSIGNMENT BY PULSED POLARIZATION TRANSFER VIA LONG-RANGE H-1-C-13 COUPLINGS [J].