SYNTHESIS AND DIOXYGEN REACTIVITY OF DINUCLEAR COPPER PHENOLATE AND COPPER PHENOL COMPLEXES WITH PYRAZOLE AND PYRIDINE DONORS

被引：59

作者：

SORRELL, TN

VANKAI, VA

机构：

[1] Department of Chemistry, University of North Carolina, Chapel Hill

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 09期

关键词：

D O I：

10.1021/ic00334a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New hybrid ligands containing pyrazole and pyridine have been prepared; and the reaction chemistry of their copper(I) derivatives has been studied. These dinucleating ligands provide three nitrogen donors to each metal ion, and a phenol or phenolate group to bridge between the metals. The reaction of the different dicopper(I) species with dioxygen follows patterns established previously for analogous pyridyl ligands; and peroxo and hydroperoxo adducts can be generated at low temperature. © 1990, American Chemical Society. All rights reserved.

引用

页码：1687 / 1692

页数：6

共 18 条

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