PI-COMPLEXATION IN THE SOLID-STATE INDUCED BY INTERMOLECULAR HYDROGEN-BONDING

被引：44

作者：

BEESON, JC ^{[1
]}

FITZGERALD, LJ ^{[1
]}

GALLUCCI, JC ^{[1
]}

GERKIN, RE ^{[1
]}

RADEMACHER, JT ^{[1
]}

CZARNIK, AW ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 11期

关键词：

D O I：

10.1021/ja00090a010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron-deficient heterocycles, such as the hexaazatriphenylenes, avoid pi-complexation in the solid state. We observe that interplane amide hydrogen bonding controls secondary structure and induces pi-complexation in the solid state of an organic hexaamide predisposed to avoid it.

引用

页码：4621 / 4622

页数：2

共 21 条

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