A MODEL OF SEMIMET HEMERYTHRIN - NMR SPECTROSCOPIC EVIDENCE OF VALENCE LOCALIZATION IN BIS(MU-CARBOXYLATO) (MU-PHENOLATO)DIIRON(II,III) COMPLEXES IN SOLUTION

被引：37

作者：

KANDA, W

MONETA, W

BARDET, M

BERNARD, E

DEBAECKER, N

LAUGIER, J

BOUSSEKSOU, A

CHARDONNOBLAT, S

LATOUR, JM

机构：

[1] CTR ETUD GRENOBLE,CEA,DEPT RECH FONDAMENTALE MAT CONDENSEE,SESAM CC LAB,F-38054 GRENOBLE 09,FRANCE

[2] WAKAYAMA UNIV,DEPT CHEM,WAKAYAMA,JAPAN

[3] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

[4] UNIV GRENOBLE 1,ELECTROCHIM ORGAN & PHOTOCHIM REDOX LAB,F-38041 GRENOBLE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 05期

关键词：

COMPLEXES WITH NITROGEN LIGANDS; COMPLEXES WITH OXYGEN LIGANDS; HEMERYTHRIN; IRON COMPOUNDS; PROTEIN MIMICS;

D O I：

10.1002/anie.199505881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new hexadentate ligand 1 was used to prepare the first FeIIFeIII complex that mimics the unsymmetrical coordination in the active site of one form of semimet hemerythrin. The different valences of the iron ions in this model complex are localized in solution, in analogy to the iron centers in the protein. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：588 / 590

页数：3

共 19 条

[1]

BEER RH, 1989, INORG CHEM, V28, P557

[2] A MIXED-VALENT, UNSYMMETRICAL (FEFEIII)-FE-II COMPLEX WITH A TERMINAL PHENOLATO LIGAND AS A MODEL FOR THE ACTIVE-SITE OF PURPLE ACID-PHOSPHATASES [J].