PHOTOADDUCT BETWEEN TRIS(1,4,5,8-TETRAAZAPHENANTHRENE)RUTHENIUM(II) AND GUANOSINE-MONOPHOSPHATE - A MODEL FOR A NEW MODE OF COVALENT BINDING OF METAL-COMPLEXES TO DNA

被引：80

作者：

JACQUET, L ^{[1
]}

KELLY, JM ^{[1
]}

DEMESMAEKER, AK ^{[1
]}

机构：

[1] FREE UNIV BRUSSELS,B-1050 BRUSSELS,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 09期

关键词：

D O I：

10.1039/c39950000913

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible light irradiation of [Ru(TAP)(3)](2+) (TAP = 1,4,5,8-tetraazaphenanthrene) in aqueous solutions containing 5'-guanosine-monophosphate (GMP) and subsequent treatment with 1 mol dm(-3) HCl yields Ru(TAP)(2)(2-TAP-G)(2+), in which the guanine moiety is bound via N-2 to C-2 of one of the TAP ligands.

引用

页码：913 / 914

页数：2

共 20 条

[1]

ABOULENEIN A, 1988, PHOTOCHEM PHOTOBIOL, V48, P27

[2]

EVANS FE, 1993, MAG RES CHEM, V31, P531

[3] PHOTOADDITION OF RUTHENIUM(II)-TRIS-1,4,5,8-TETRAAZAPHENANTHRENE TO DNA AND MONONUCLEOTIDES [J].