CORRELATIONS OF VALUES OF AVERAGE ENERGY-TRANSFER FROM HIGHLY EXCITED POLYATOMIC-MOLECULES WITH HEATS OF VAPORIZATION AND BOILING TEMPERATURES

被引：16

作者：

OREF, I

机构：

[1] Department of Chemistry, Technion - Israel Institute of Technology

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 15期

关键词：

D O I：

10.1021/j100194a039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Correlations of the average energy transferred in a highly excited polyatomic molecule-bath gas binary collision with the heat of vaporization and boiling point of the bath gas are presented. It is shown that a unique correlation exists between the logarithms of the average energy transferred in a collision and the values of the two quantities reported above. Examples are given for excited toluene, azulene, and substituted cycloheptatriene collisions with mono- and polyatomic bath gases.

引用

页码：6308 / 6313

页数：6

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