SYNTHESIS OF STERICALLY RIGID MACROCYCLES BY THE USE OF PRESSURE-INDUCED REPETITIVE DIELS-ALDER REACTIONS

被引：41

作者：

BENKHOFF, J

BOESE, R

KLARNER, FG

WIGGER, AE

机构：

[1] UNIV GESAMTHSCH ESSEN,INST ORGAN CHEM,D-45117 ESSEN,GERMANY

[2] UNIV GESAMTHSCH ESSEN,INST ANORGAN CHEM,D-45117 ESSEN,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 01期

关键词：

D O I：

10.1016/0040-4039(94)88165-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syntheses of the syn-dimethanotetrahydroanthracene and -tetracene derivatives 2a.d and 6a,b are described. Highly stereoselective, pressure-induced repetitive Diels-Alder reactions of these bis-dienophiles with bisdiene 7 lead to the sterically rigid macrocycles 10a, 10d, 13a and 14a,b having well defined cavities of different size.

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页码：73 / 76

页数：4

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