EFFECTS OF CHAIN CONFIGURATIONAL PROPERTIES ON THE STRESS-STRAIN BEHAVIOR OF GLASSY LINEAR-POLYMERS

被引：48

作者：

MCKECHNIE, JI ^{[1
]}

HAWARD, RN ^{[1
]}

BROWN, D ^{[1
]}

CLARKE, JHR ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

MACROMOLECULES | 1993年 / 26卷 / 01期

关键词：

D O I：

10.1021/ma00053a030

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We have performed a systematic study of the relationship between polymer structure and the phenomenon of strain hardening by employing controlled stress molecular dynamics computer simulation in conjunction with a simple polyethylene-like model. We find that varying the sample preparation history produces materials which, while being chemically identical, differ profoundly in their response to an applied stress.

引用

页码：198 / 202

页数：5

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