HYDROXYLAMINE, HYDRAZINE, AND DIAZENE AS UNIDENTATE LIGANDS IN OSMIUM AND RUTHENIUM COMPLEXES

被引：58

作者：

CHENG, TY

PONCE, A

RHEINGOLD, AL

HILLHOUSE, GL

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1002/anie.199406571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unidentate trans‐HNNH ligand in 1 (M = Os) is the most significant structural feature of this surprisingly stable compound. The positions of the two H atoms in the diazene were located and refined in the X‐ray structural analysis. Compound 1 and the analogous Ru complex were prepared by the oxidation of the corresponding hydrazine complexes. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：657 / 659

页数：3

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