THE EFFECT OF WATER ON THE TRANSPORT OF OXYGEN THROUGH NYLON-6 FILMS

被引：43

作者：

GAVARA, R

HERNANDEZ, RJ

机构：

[1] MICHIGAN STATE UNIV,SCH PACKAGING,E LANSING,MI 48824

[2] CSIC,E-46010 VALENCIA,SPAIN

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1994年 / 32卷 / 14期

关键词：

NYLON-6; DIFFUSION OF OXYGEN; BIMODAL DIFFUSION; EFFECT OF WATER CONTENT;

D O I：

10.1002/polb.1994.090321408

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of presence of water on the transport of oxygen through films of Nylon-6 was evaluated at 5, 23, and 40-degrees-C by permeation experiments. Through the oxygen permeability experiments it was found that the diffusion of oxygen through Nylon-6 is not a simple Fickian process and the total diffusion process can be expressed by a bimodal diffusion mechanism. Permeability, solubility, and diffusion coefficients were determined as a function of water activity for both mechanisms. The effect of sorbed water on the oxygen diffusion and solubility in the polymer is presented as a function of the state of water in the polymer and as a result of the molecular competition between water and oxygen. (C) 1994 John Wiley & Sons, Inc.

引用

页码：2375 / 2382

页数：8

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