SYNTHESIS AND STUDY OF THERMAL AND ELECTRICAL BEHAVIOR OF SOME POLYAROMATIC AMINES

被引：21

作者：

RAWAT, B ^{[1
]}

KANSARA, SS ^{[1
]}

RAMA, HS ^{[1
]}

机构：

[1] MAHARAJA SAYAJIRAO UNIV BARODA,FAC SCI,DEPT CHEM,BARODA 390002,GUJARAT,INDIA

来源：

POLYMER INTERNATIONAL | 1991年 / 26卷 / 04期

关键词：

POLYBENZIDENE; ELECTROCHEMICAL SYNTHESIS; ELECTRICAL CONDUCTIVITY; DOPING; THERMAL STABILITY; ACTIVATION ENERGY;

D O I：

10.1002/pi.4990260406

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Samples of polyaromatic amines were synthesised by chemical and electrochemical methods, using different amounts of electrolytes for the purpose of doping the polymer. These polymers were found to show electrical conductivity in the range 10(-12)-10(-6) S/cm. A study of conductivity at various temperatures indicates the semiconducting behaviour of these polymers. Thermal analysis shows that these polymers have high thermal stability.

引用

页码：233 / 238

页数：6

共 10 条

[1]

ANDERSON DA, 1961, J POLYM SCI, V84, P253

[2]

[Anonymous], 1862, J CHEM SOC, DOI [DOI 10.1039/JS8621500161, 10.1039/JS8621500161]

[3] A SIMPLE, SENSITIVE GRAPHICAL METHOD OF TREATING THERMOGRAVIMETRIC ANALYSIS DATA [J].

BROIDO, A .

JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1969, 7 (10PA) :1761-&

[4]

DIAZ AF, 1988, ELECTROCHEMISTRY ELE, P114

[5]

Green A. G., 1910, J CHEM SOC, V97, P2388

[6] HIGHLY CONDUCTING CHARGE-TRANSFER COMPLEXES OF POLY(PARA-PHENYLENE) [J].

IVORY, DM ;

MILLER, GG ;

SOWA, JM ;

SHACKLETTE, LW ;

CHANCE, RR ;

BAUGHMAN, RH .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (03) :1506-1507

[7]

MACDIARMID AG, 1987, SYNTHETIC METAL, V18, P3793

[8] STRUCTURAL STUDIES OF ANILINE - SUBSTITUTED ANILINE COPOLYMERS BY XPS [J].

NEOH, KG ;

KANG, ET ;

TAN, KL .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1990, A27 (07) :933-946

[9]

PETHRICK RA, 1990, ELECTROCHEICAL SCI T, V2

[10] SYNTHESIS AND ELECTROCHEMISTRY OF ALKYL RING-SUBSTITUTED POLYANILINES [J].

WEI, Y ;

FOCKE, WW ;

WNEK, GE ;

RAY, A ;

MACDIARMID, AG .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (01) :495-499

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