MOLECULAR CONTAINER COMPOUNDS

被引：398

作者：

CRAM, DJ

机构：

[1] Department of Chemistry and Biochemistry, University of California at Los Angeles, Los Angeles, CA 90024

来源：

NATURE | 1992年 / 356卷 / 6364期

关键词：

D O I：

10.1038/356029a0

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Rigid, hollow organic host compounds have been designed and synthesized with interior cavities large enough to incarcerate organic guest compounds. Some of these hosts are closed-surface spheres whose guest molecules are permanently incarcerated during synthesis. Other hosts contain portals in their shells, shaped to allow the passage only of complementary guest molecules between the inner and bulk phases. The inner phases uniquely constrain guest movements, provide a medium for reactions, and shelter molecules that self-destruct in bulk phases.

引用

页码：29 / 36

页数：8

共 33 条

[1] CYCLOBUTADIENE [J].