DEALKYLATION OF AN ORGANOIMIDO LIGAND LEADING TO A BINUCLEAR (MU-NITRIDO) COMPLEX OF MOLYBDENUM(IV) - STRUCTURE OF THE [CL-3(PY)(2)MONMO(PY)(2)CL-3](-) ANION

被引：9

作者：

DU, YH ^{[1
]}

RHEINGOLD, AL ^{[1
]}

MAATTA, EA ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridine abstracts an allyl group from the Mo-VI allylimido complex [CH2=CH-CH2-N drop MoCl4(thf)], leading to the ultimate formation of the N-allylpyridinium salt of an unusual mu-nitrido binuclear Mo-IV species,[CH2=CH-CH2-py][Cl-3(py)(2)MoNMo(py)(2)Cl-3].

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页码：2163 / 2164

页数：2

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