OPTICALLY-ACTIVE LACTONES FROM A BAEYER-VILLIGER-TYPE METAL-CATALYZED OXIDATION WITH MOLECULAR-OXYGEN

被引：201

作者：

BOLM, C ^{[1
]}

SCHLINGLOFF, G ^{[1
]}

WEICKHARDT, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple, mild, and enantioselective! Oxygen reacts with ketone 1 in the presence of pivalaldehyde (R  tBu) and a chiral copper complex (cat.*) to give lactone 2 in 47% yield and 69% ee. Other enantioselective Baeyer—Villiger‐type oxidations had previously only been achieved with the help of enzymes. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1848 / 1849

页数：2

共 31 条

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