SOLID-STATE REACTIVITY OF TRIACETYLENES

被引：61

作者：

ENKELMANN, V

机构：

[1] Max-Planck-Institut für Polymerforschung, Postfach 3148

来源：

CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 08期

关键词：

D O I：

10.1021/cm00044a035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Crystal structures of four triacetylenes are reported. Three of the investigated monomers polymerize in the solid state. In all of these cases the polymerization proceeds by a 1,4 addition and is a nonunique topochemical reaction. Therefore, the reactions are not single-crystal-to-single-crystal processes. Possible strategies for the design of reactive triacetylenes undergoing 1,6 addition in the solid state are discussed.

引用

页码：1337 / 1340

页数：4

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