CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - THEORY OF DOUBLE ELECTRODES

被引：32

作者：

COMPTON, RG ^{[1
]}

COLES, BA ^{[1
]}

FISHER, AC ^{[1
]}

机构：

[1] UNIV BATH,DEPT CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 09期

关键词：

D O I：

10.1021/j100060a035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theoretical treatment is presented which permits the computation of transient effects at double-channel electrodes. In particular, the current response of a downstream ''detector'' electrode to a potential step at an upstream ''generator'' electrode is established, and it is shown that such experiments can provide unique information both about the homogeneous behavior of electrogenerated species and about interfacial reactions occurring at the solid/liquid interface which forms part of the wall of the flow cell between the two electrodes.

引用

页码：2441 / 2445

页数：5

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