SYNTHESIS OF UNSYMMETRICAL BIARYL KETONES VIA PALLADIUM-CATALYZED CARBONYLATIVE CROSS-COUPLING REACTION OF ARYLBORONIC ACIDS WITH IODOARENES

被引：151

作者：

ISHIYAMA, T

KIZAKI, H

MIYAURA, N

SUZUKI, A

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)60409-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling reaction between arylboronic acids, carbon monoxide (1 atm), and aryl iodides in the presence of palladium catalyst and base provided unsymmetrical biaryl ketones in high yields. The choice of a suitable base and solvent was essential to achieve selective formation of the unsymmetrical biaryl ketone without a biaryl by-product.

引用

页码：7595 / 7598

页数：4

共 15 条

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