THE LUMINESCENCE PROPERTIES OF OCTAHEDRAL AND TETRAHEDRAL MOLYBDATE COMPLEXES

被引：48

作者：

WIEGEL, M

BLASSE, G

机构：

[1] Debye Research Institute, University of Utrecht, 3508 TA Utrecht

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1992年 / 99卷 / 02期

关键词：

D O I：

10.1016/0022-4596(92)90327-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The luminescence properties of MoO2-4 and MoO6-6 complexes are reported and discussed, using new data on La2MoO6 and ordered perovskites. In the molybdate complexes the probability of nonradiative return to the ground state decreases if the lowest absorption band is at higher energy and the Stokes shift decreases. In the perovskite Ba3Y2MoO9 the Mo6+ and Y3+ ions show 1 : 2 ordering. A small amount of disorder is probably due to interchange of some of the Ba2+ and Y3+ ions. © 1992 Academic Press, Inc.

引用

页码：388 / 394

页数：7

共 15 条

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