THEORY OF CORE-LEVEL SPECTROSCOPY IN ACTINIDE SYSTEMS

被引：41

作者：

KOTANI, A ^{[1
]}

OGASAWARA, H ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT PHYS, SENDAI, MIYAGI 980, JAPAN

来源：

PHYSICA B-CONDENSED MATTER | 1993年 / 186-88卷

关键词：

D O I：

10.1016/0921-4526(93)90485-O

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We analyze the actinide 4f core X-ray photoemission spectra for actinide dioxide series, ThO2, UO2-BkO2, using the impurity Anderson model. Systematic variations of physical parameters, such as the charge transfer energy and the covalency hybridization strength, are investigated with the change of the actinide elements. We also calculate uranium 5d core X-ray absorption spectra (5d-XAS) of UO2 and other U compounds taking into account the effect of multiplet coupling. We discuss an important role of the interplay between the intra-atomic multiplet coupling and the inter-atomic hybridization on the 5d-XAS.

引用

页码：16 / 20

页数：5

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