HYDROGENATION OF EPOXIDIZED NATURAL-RUBBER IN THE PRESENCE OF PALLADIUM ACETATE CATALYST

被引：28

作者：

BHATTACHARJEE, S

BHOWMICK, AK

AVASTHI, BN

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KHARAGPUR 721302,W BENGAL,INDIA

[2] INDIAN INST TECHNOL,CTR RUBBER TECHNOL,KHARAGPUR 721302,W BENGAL,INDIA

来源：

POLYMER | 1993年 / 34卷 / 24期

关键词：

EPOXIDIZED NATURAL RUBBER; PALLADIUM ACETATE; HYDROGENATION;

D O I：

10.1016/0032-3861(93)90265-C

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Epoxidized natural rubber has been selectively hydrogenated in the presence of a homogeneous palladium acetate catalyst. The hydrogenated product has been characterized by infra-red and nuclear magnetic resonance spectroscopies. No change is noted in the epoxy content of the polymer after the reaction. The catalyst is highly selective in reducing carbon-carbon double bonds in the presence of epoxy groups. Natural rubber has also been hydrogenated for a comparative study. The rate constant of hydrogenation is decreased with increase in epoxy content of the polymer.

引用

页码：5168 / 5173

页数：6

共 25 条

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Barnard C.F.J., 1987, COMPREHENSIVE COORDI, V5, P1099

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