REACTION BRANCHING AS A MECHANISTIC ALTERNATIVE TO TUNNELING IN EXPLAINING ANOMALOUS TEMPERATURE-DEPENDENCIES OF KINETIC ISOTOPE EFFECTS

被引：16

作者：

THIBBLIN, A

机构：

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1988年 / 1卷 / 03期

关键词：

D O I：

10.1002/poc.610010306

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：161 / 167

页数：7

共 14 条

[1]

AHLBERG P, 1985, 2ND P INT S SYNTH AP, P89

[2] USE OF KINETIC ISOTOPE-EFFECTS IN MECHANISM STUDIES - ANOMALOUS ARRHENIUS PARAMETERS IN STUDY OF ELIMINATION-REACTIONS [J].

KOCH, HF ;

DAHLBERG, DB ;

MCENTEE, MF ;

KLECHA, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (04) :1060-1061

[3] PROTON-TRANSFER REACTIONS .5. AN OBSERVED PRIMARY KINETIC ISOTOPE EFFECT THAT INCREASES WITH INCREASING TEMPERATURE [J].

KOCH, HF ;

KOCH, AS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (16) :4536-4539

[4] USE OF KINETIC ISOTOPE EFFECTS IN MECHANISM STUDIES .4. CHLORINE ISOTOPE EFFECTS ASSOCIATED WITH ALKOXIDE-PROMOTED DEHYDROCHLORINATION REACTIONS [J].

KOCH, HF ;

MCLENNAN, DJ ;

KOCH, JG ;

TUMAS, W ;

DOBSON, B ;

KOCH, NH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (07) :1930-1937

[5]

KOCH HF, 1982, J AM CHEM SOC, V102, P6102

[6]

LEWIS ES, 1975, PROTON TRANSFER REAC, pCH10

[7]

Melander L, 1980, REACTION RATES ISOTO

[8] DEPROTONATION OF METHYLARENE CATION RADICALS IN ACETONITRILE - AN UNEXPECTED 2ND-ORDER MECHANISM [J].

PARKER, VD ;

TILSET, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (20) :6371-6377

[9] MECHANISM OF ELIMINATION FROM A TIGHTLY HYDROGEN-BONDED CARBANION [J].

THIBBLIN, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (02) :92-93

[10] DEPROTONATION OF ION-PAIRS IN AQUEOUS SOLVENT - COMPETING BIMOLECULAR AND SOLVOLYTIC ELIMINATION-REACTIONS [J].

THIBBLIN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) :2071-2076

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