CHIRAL INDUCTION IN A FACILE THIO-CLAISEN REARRANGEMENT

被引：12

作者：

REDDY, KV ^{[1
]}

RAJAPPA, S ^{[1
]}

机构：

[1] NATL CHEM LAB,DIV ORGAN CHEM SYNTH,POONA 411008,MAHARASHTRA,INDIA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)74788-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylation of nitrothioacetamides proceeds by initial S-allylation followed by an extremely facile thio-Claisen rearrangement. The diastereomeric excess in the allylation of N-nitrothioacetyl (L-)proline ethyl ester (4) is 66%.

引用

页码：7957 / 7960

页数：4

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