ELECTROCHEMICAL INVESTIGATIONS ON METHYLENEPHOSPHINES AND RELATED SYSTEMS

被引：17

作者：

SCHOELLER, WW

NIEMANN, J

THIELE, R

HAUG, W

机构：

[1] Fakultät für Chemie, Universität Bielefeld, D-4800

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 03期

关键词：

METHYLENEPHOSPHINES; VOLTAMMETRY; CYCLIC;

D O I：

10.1002/cber.19911240302

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical investigations on a selection of methylenephosphines 1 and related systems are reported. They are shown to possess an irreversible oxidation and reduction wave. An exception is diaminodiphosphene, which reversibly forms a radical anion. A relative ordering of frontier orbitals is possible, based on the redox properties of these systems.

引用

页码：417 / 421

页数：5

共 51 条

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