A PLATINUM CHLORO (FLUOROARYL)PHOSPHINE COMPLEX

被引：13

作者：

SCHAEFER, WP ^{[1
]}

LYON, DK ^{[1
]}

LABINGER, JA ^{[1
]}

BERCAW, JE ^{[1
]}

机构：

[1] CALTECH,BECKMAN INST,PASADENA,CA 91125

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192001008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Dichlorobis[tris(pentafluorophenyl)-phosphine]platinum(II), [PtCl2{P(C6F5)3}2], M(r) = 1330.29, triclinic, P1BAR, a = 9.536 (4), b = 11.221 (2), c = 11.613 (1) angstrom, alpha = 62.55 (1), beta = 65.81 (2), gamma = 73.05 (2)-degrees, V = 997.8 (4) angstrom3, Z = 1, D(x) = 2.21 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 39.27 cm-1, F(000) = 628, room temperature, R = 0.034 for 3497 reflections with F(o)2 > 0. The molecule is centrosymmetric, with Pt-Cl distance 2.304 (2) and Pt-P 2.280 (1) angstrom, and P-Pt-Cl angle 94.8 (1)-degrees. The C-P distances average 1.824 (4) angstrom, slightly longer than normal, and the pentafluorophenyl groups all have small [116.3 (3)-degrees] angles at the c atom bonded to P.

引用

收藏

页码：1582 / 1584

页数：3

相关论文

共 20 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[2]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P149

[3] RESTRICTED ROTATION AND PREFERRED CONFORMATIONS IN TRIS(PENTAFLUOROPHENYL)-PHOSPHINE PLATINUM(II) COMPLEXES - MECHANISM OF HELICITY REVERSAL IN A COORDINATED TRIARYLPHOSPHINE [J].

DOCHERTY, JB ;

RYCROFT, DS ;

SHARP, DWA ;

WEBB, GA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (07) :336-337

[4]

DUCHAMP DJ, 1964, AM CRYSTALLOGR ASS M, P29

[5] (FLUOROALKYL)PHOSPHINE CHEMISTRY OF MOLYBDENUM - SYNTHESIS, STRUCTURE, AND PROPERTIES OF MOLYBDENUM(0) ARENE COMPLEXES (ETA-6-C6H5R)MO[(C2F5)2PCH2CH2P(C2F5)2](L) [J].

ERNST, MF ;

RODDICK, DM .

ORGANOMETALLICS, 1990, 9 (05) :1586-1594

[6] CHELATE BINDING PREFERENCES IN CPML4 COMPLEXES - PREPARATION AND STRUCTURE OF TRANS-(ETA-5-C5H5)MO[(C6F5)2PCH2CH2P(C6F5)2](CO)CL [J].

ERNST, MF ;

RODDICK, DM .

INORGANIC CHEMISTRY, 1990, 29 (18) :3627-3630

[7] SYNTHESIS AND COORDINATION PROPERTIES OF BIS(BIS(PENTAFLUOROETHYL)PHOSPHINO)ETHANE [J].

ERNST, MF ;

RODDICK, DM .

INORGANIC CHEMISTRY, 1989, 28 (09) :1624-1627

[8] ADDUCTS OF COORDINATION-COMPOUNDS .11. ISOMERISM AND SOLVATION OF DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II) [J].

GILLARD, RD ;

PILBROW, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (21) :2320-2325

[9] MASS SPECTROMETRY OF PLATINUM(II) COMPLEXES - COMPARISON OF CIS AND TRANS ISOMERS - FRAGMENTATION AND REARRANGEMENT PATHWAYS [J].

HAAKE, P ;

MASTIN, SH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (25) :6823-&

[10] STRUCTURE OF DISODIUM TRANS-BIS(2,6-PYRIDINEDICARBOXYLATO-O,N)PLATINATE(II) HEXAHYDRATE [J].

HERRING, AM ;

HENLING, L ;

LABINGER, JA ;

BERCAW, JE .

INORGANIC CHEMISTRY, 1991, 30 (04) :851-853