REACTIONS OF AMINES WITH ARENE RUTHENIUM COMPLEXES - CRYSTAL-STRUCTURES OF [(1,3,5-ME3C6H3) RUCL2(HNC5H10)] AND [(1,3,5-ME3C6H3)RUCL2(NC5H5)]

被引：14

作者：

CARTER, L ^{[1
]}

DAVIES, DL ^{[1
]}

FAWCETT, J ^{[1
]}

RUSSELL, DR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)88200-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of primary and secondary amines have been reacted with the dimers [(arene)RuCl2]2 to give simple adducts [(arene)RuCl2(NHRR1)]. We have structurally characterized the complexes [(1,3,5-Me3C6H3)RuCl2(HNC5H10)] and [(1,3,5-Me3C6H3) RuCl2(NC5H5)]. Amine exchange reactions have been performed to assess the relative stabilities of these adducts. With certain ligands complex cations, [(1,3,5-Me3C6H3)RuCl (NHRR1)2]+, can form, although these are more easily prepared by reaction in the presence of AgBF4.

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页码：1123 / 1128

页数：6

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