DINUCLEAR (CU/CU, NI/NI, V/V AND FE/FE) COMPLEXES OF A NOVEL OXAMIDE-TYPE LIGAND COORDINATING IN THE TRANS CONFORMATION

被引：12

作者：

LAURENT, JP ^{[1
]}

COSTES, JP ^{[1
]}

PRADIE, G ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,CNRS,CHIM COORDINAT LAB,UP 8241,F-31077 TOULOUSE,FRANCE

来源：

INORGANICA CHIMICA ACTA | 1993年 / 213卷 / 1-2期

关键词：

D O I：

10.1016/S0020-1693(00)83814-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of an original N,N'-disubstituted oxamide derivative are reported. This compound is distinguished by the occurrence of substituents with terminal NH2 groups which can be used in further reactions. Thus by reaction with salicylaldehyde one obtains a new dinucleating ligand which affords the first examples of vanadium(IV) and iron(III) oxamido-bridged dinuclear complexes. The spectroscopic characteristics and magnetic properties of these complexes and the related nickel(II) and copper(II) complexes are reported.

引用

页码：57 / 63

页数：7

共 60 条

[31] MOLECULAR TOPOLOGY AND EXCHANGE INTERACTION - SYNTHESIS AND MAGNETIC-PROPERTIES OF [CUII3CDII], [CUII3NIII], [CUII3MNII] TETRANUCLEAR SPECIES [J].

LLORET, F ;

JOURNAUX, Y ;

JULVE, M .

INORGANIC CHEMISTRY, 1990, 29 (20) :3967-3972

[32] A NOVEL MOLECULAR BASED FERROMAGNET ORDERING AT 14-K [J].

LLORET, F ;

NAKATANI, K ;

JOURNAUX, Y ;

KAHN, O ;

YU, P ;

RENARD, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) :642-643

[33] OXAMIDATO COMPLEXES .5. INFLUENCE OF THE STERIC CONSTRAINTS ON THE COMPLEX-FORMATION BETWEEN COPPER(II) AND N,N'(ALKYL-SUBSTITUTED)OXAMIDES - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU2(MAPOX)(N3)2]N (H2MAPOX = N,N'-BIS[3-(METHYLAMINO)PROPYL]OXAMIDE) [J].

LLORET, F ;

JULVE, M ;

REAL, JA ;

FAUS, J ;

RUIZ, R ;

MOLLAR, M ;

CASTRO, I ;

BOIS, C .

INORGANIC CHEMISTRY, 1992, 31 (13) :2956-2961

[34] OXAMIDATO COMPLEXES .1. A STUDY OF THE FORMATION OF COMPLEXES BETWEEN COPPER(II) AND H2PMOX (H2PMOX = N,N'-BIS(2-PYRIDYLMETHYL)OXAMIDE) - SYNTHESIS, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF THE ALTERNATING-CHAIN COMPOUND [CU2(PMOX)(H2PMOX)(H2O)2](NO3)2.8H2O [J].

LLORET, F ;

JULVE, M ;

FAUS, J ;

JOURNAUX, Y ;

PHILOCHELEVISALLES, M ;

JEANNIN, Y .

INORGANIC CHEMISTRY, 1989, 28 (19) :3702-3706

[35] OXAMIDATO COMPLEXES .3. A STUDY OF THE FORMATION OF HOMOPOLYMETALLIC AND HETEROPOLYMETALLIC CU(II)-H2APOX-M(II) COMPLEXES (H2APOX = N,N'-BIS(3-AMINOPROPYL)OXAMIDE - M(II) = MN, CO, NI, CU, ZN, CD) - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU2(APOX)(NCO)2] [J].

LLORET, F ;

JULVE, M ;

FAUS, J ;

RUIZ, R ;

CASTRO, I ;

MOLLAR, M ;

PHILOCHELEVISALLES, M .

INORGANIC CHEMISTRY, 1992, 31 (05) :784-791

[36] OXAMIDATO COMPLEXES .2. COPPER(II) AND NICKEL(II) COMPLEXES WITH OXAMIDE-N,N'-DIACETIC ACID - SOLUTION STUDY, SYNTHESIS, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES [J].

LLORET, F ;

SLETTEN, J ;

RUIZ, R ;

JULVE, M ;

FAUS, J ;

VERDAGUER, M .

INORGANIC CHEMISTRY, 1992, 31 (05) :778-784

[37] SYNTHESIS OF PHENOXO-BRIDGED DICOPPER(II) COMPLEXES OF N-(2-AMINOALKYL)SALICYLALDIMINES AND THEIR USE IN THE FORMATION OF MONOHALOGENO-COMPLEXES AND NON-SYMMETRICAL QUADRIDENTATE SCHIFF-BASE COMPLEXES [J].

MANDAL, SK ;

NAG, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2839-2841

[38] SYNTHESIS, MAGNETISM AND CRYSTAL-STRUCTURE OF [V2O2(MU-OH)2(TETRAKIS(2-PYRIDYLMETHYL)ETHYLENEDIAMINE)]I2.4H2O - A BINUCLEAR COMPLEX CONTAINING THE SYN-(VO(MU-OH)2VO)2+ CORE [J].

NEVES, A ;

WEIGHARDT, K ;

NUBER, B ;

WEISS, J .

INORGANICA CHIMICA ACTA, 1988, 150 (02) :183-187

[39] BINUCLEAR COPPER(II) COMPLEXES BRIDGED BY N,N'-DISUBSTITUTED OXAMIDES CONTAINING THIOETHER DONOR GROUPS [J].

NONOYAMA, K ;

OJIMA, H ;

NONOYAMA, M .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (01) :13-18

[40] SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH MU-OXAMIDO, MU-OXAMATO, AND MU-OXALATO-BRIDGES [J].

NONOYAMA, K ;

OJIMA, H ;

OHKI, K ;

NONOYAMA, M .

INORGANICA CHIMICA ACTA-ARTICLES, 1980, 41 (02) :155-159

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