IRON-CATALYZED ALLYLIC AMINATION

被引：74

作者：

JOHANNSEN, M ^{[1
]}

JORGENSEN, KA ^{[1
]}

机构：

[1] AARHUS UNIV,DEPT CHEM,DK-8000 AARHUS,DENMARK

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 01期

关键词：

D O I：

10.1021/jo00080a034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transition-metal-catalyzed allylic amination of alkenes is studied. A screening of different transition-metal complexes reveals that iron complexes, especially iron phthalocyanin, have the best catalytic properties, using phenylhydroxylamine as the nitrogen-fragment donor. The iron phthalocyanin-catalyzed reaction has been studied for a variety of alkenes and the best yields are obtained for alkenes substituted with aromatic groups. The scope of this reaction is discussed.

引用

页码：214 / 216

页数：3

共 21 条

[1] INTRAMOLECULAR NITRENE C-H INSERTIONS MEDIATED BY TRANSITION-METAL COMPLEXES AS NITROGEN ANALOGS OF CYTOCHROME-P-450 REACTIONS
BRESLOW, R
GELLMAN, SH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) : 6728 - 6729
[2] TOSYLAMIDATION OF CYCLOHEXANE BY A CYTOCHROME-P-450 MODEL
BRESLOW, R
GELLMAN, SH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (24) : 1400 - 1401
[3] CALDER A, 1988, ORG SYNTH, V6, P803
[4] BIS(OXAZOLINE) COPPER-COMPLEXES AS CHIRAL CATALYSTS FOR THE ENANTIOSELECTIVE AZIRIDINATION OF OLEFINS
EVANS, DA
FAUL, MM
BILODEAU, MT
ANDERSON, BA
BARNES, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 5328 - 5329
[5] COPPER-CATALYZED AZIRIDINATION OF OLEFINS BY (N-(PARA-TOLUENESULFONYL)IMINO)PHENYLIODINANE
EVANS, DA
FAUL, MM
BILODEAU, MT
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (24) : 6744 - 6746
[6] PALLADIUM ASSISTED INTRAMOLECULAR AMINATION OF OLEFINS - NEW SYNTHESIS OF INDOLES
HEGEDUS, LS
ALLEN, GF
WATERMAN, EL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) : 2674 - 2676
[7] ASYMMETRIC ALKENE AZIRIDINATION WITH READILY AVAILABLE CHIRAL DIIMINE-BASED CATALYSTS
LI, Z
CONSER, KR
JACOBSEN, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 5326 - 5327
[8] 1ST D0 METALLOOXAZIRIDINES - AMINATION OF OLEFINS
LIEBESKIND, LS
SHARPLESS, KB
WILSON, RD
IBERS, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (22) : 7061 - 7063
[9] ALLYLIC AMINATION OF ALKENES BY TOSYLIMINOIODOBENZENE - MANGANESE PORPHYRINS AS SUITABLE CATALYSTS
MAHY, JP
BEDI, G
BATTIONI, P
MANSUY, D
[J]. TETRAHEDRON LETTERS, 1988, 29 (16) : 1927 - 1930
[10] AZIRIDINATION OF ALKENES CATALYZED BY PORPHYRINIRONS - SELECTION OF CATALYSTS FOR OPTIMAL EFFICIENCY AND STEREOSPECIFICITY
MAHY, JP
BEDI, G
BATTIONI, P
MANSUY, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1988, (08): : 1517 - 1524

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