SOLUBLE POLYANILINES PREPARED BY OXIDATIVE POLYMERIZATION OF DIMETHYLANILINES

被引：11

作者：

KITANI, A

SATOGUCHI, K

TANG, HQ

ITO, S

SASAKI, K

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima, 724, Kagamiyama

来源：

SYNTHETIC METALS | 1995年 / 69卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02388-F

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrochemical polymerization of ring-substituted dimethylaniline was performed in aqueous acid solutions to obtain soluble conducting polyaniline. The conductivity values of polydimethylanilines obtained were in the range of 10(-1) similar to 10(-7) Scm(-1) depending on the preparation conditions. The molar masses of the oxidation products were in the order of 10(3) g regardless of the monomer structure. These conductive oligomers were easily soluble in polar organic solvents. Soluble conducting oligomers were also obtained by chemical polymerization with iron (III) species.

引用

页码：131 / 132

页数：2