GAS-PHASE CHEMISTRY OF THE DIMETHYLALUMINUM OXIDE ANION, [(CH3)2ALO]-

被引：6

作者：

DAMRAUER, R

KREMPP, M

机构：

[1] Department of Chemistry, University of Colorado at Denver, Denver

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a085

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Flowing afterglow‒selected ion flow tube technology (FA‒SIFT) has been used to generate and select [(CH3)2AlO]- (1), whose ion‒molecule chemistry has been extensively studied. This ion reacts with several fluoroaromatics to give [(CH3)2Al(F)OH]-, which is formally an HF adduct of 1. Similarly, H2O, HCl, H2S, and CH3SH formally add to 1 in reactions with carboxylic acids, chloroaromatics, thiolacetic acid, and methyl disulfide, respectively. Finally, several smaller neutral molecules react to give products that are formulated as adducts. © 1990, American Chemical Society. All rights reserved.

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页码：1353 / 1355

页数：3

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