SELECTIVE CHIRALITY - A CLOSER EXAMINATION

被引：1

作者：

BONNER, WA

机构：

[1] Department of Chemistry, Stanford University, 94305, CA

来源：

ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE | 1990年 / 20卷 / 05期

关键词：

D O I：

10.1007/BF01808135

中图分类号：

Q [生物科学];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The recent suggestion (Root-Bernstein, 1982) that the homochirality of amino acids and sugars in the current biosphere may have originated as a result of novel organic 'selector molecules' is examined critically. It is concluded that such selector molecules are non-existent as described, and that their postulation is based on chemical and stereochemical misconceptions.

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页码：411 / 417

页数：7

相关论文

共 15 条

[1] NEW INSIGHTS INTO THE ORIGIN OF BIOLOGICAL CHIRALITY [J].

BLUMENTHAL, SJ .

BIOESSAYS, 1984, 1 (06) :258-260

[2]

BLUMENTHAL SJ, 1985, BIOESSAYS, V114, P665

[3] How important is parity violation for molecular and biomolecular chirality? [J].

Quack, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) :4618-4630

[4] CHIRAL RESOLUTIONS, ASYMMETRIC-SYNTHESIS AND AMPLIFICATION OF ENANTIOMERIC EXCESS [J].

DEMIN, M ;

LEVY, G ;

MICHEAU, JC .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1988, 85 (05) :603-619

[5] DETECTION OF INTRAMOLECULAR MOBILITY BY NMR SPECTROSCOPY .13. DETECTION OF HINDERED ROTATION AND INVERSION BY NMR SPECTROSCOPY [J].

KESSLER, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (03) :219-&

[6]

LEHN JM, 1970, FORTSCHR CHEM FORSCH, V15, P311

[7]

NYGAARD L, 1969, J MOL STRUCT, V3, P491

[8] CHEMICAL EVOLUTION AND THE ORIGIN OF LIFE - BIBLIOGRAPHY SUPPLEMENT 1982 [J].

PLEASANT, LG ;

PONNAMPERUMA, C .

ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE, 1984, 15 (01) :55-69

[9]

PORTELLI C, 1987, SPECULAT SCI TECHNOL, V10, P89

[10]

PORTELLI C, 1987, J THEOR BIOL, V93, P93