SUBSTRATE RADICAL INTERMEDIATES ARE INVOLVED IN THE SOLUBLE METHANE MONOOXYGENASE CATALYZED OXIDATIONS OF METHANE, METHANOL AND ACETONITRILE

被引：30

作者：

DEIGHTON, N

PODMORE, ID

SYMONS, MCR

WILKINS, PC

DALTON, H

机构：

[1] UNIV WARWICK,DEPT BIOL SCI,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[2] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/c39910001086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-centred radical intermediates have been identified by spin-trapping in the soluble methane monooxygenase catalysed hydroxylation of alkyl substrates.

引用

页码：1086 / 1087

页数：2

共 18 条

[1] SPIN TRAPPING - ELECTRON-SPIN-RESONANCE PARAMETERS OF SPIN ADDUCTS [J].

BUETTNER, GR .

FREE RADICAL BIOLOGY AND MEDICINE, 1987, 3 (04) :259-303

[2] RESOLUTION OF METHANE MONO-OXYGENASE OF METHYLOCOCCUS-CAPSULATUS-BATH INTO 3 COMPONENTS - PURIFICATION AND PROPERTIES OF COMPONENT-C, A-FLAVOPROTEIN [J].

COLBY, J ;

DALTON, H .

BIOCHEMICAL JOURNAL, 1978, 171 (02) :461-468

[3] CHARACTERIZATION OF THE 2ND PROSTHETIC GROUP OF THE FLAVOENZYME NADH-ACCEPTOR REDUCTASE (COMPONENT-C) OF THE METHANE MONO-OXYGENASE FROM METHYLOCOCCUS-CAPSULATUS (BATH) [J].

COLBY, J ;

DALTON, H .

BIOCHEMICAL JOURNAL, 1979, 177 (03) :903-908

[4] SOLUBLE METHANE MONO-OXYGENASE OF METHYLOCOCCUS-CAPSULATUS-(BATH) - ABILITY TO OXYGENATE NORMAL-ALKANES, NORMAL-ALKENES, ETHERS, AND ALICYCLIC, AROMATIC AND HETEROCYCLIC-COMPOUNDS [J].

COLBY, J ;

STIRLING, DI ;

DALTON, H .

BIOCHEMICAL JOURNAL, 1977, 165 (02) :395-402

[5] TOWARDS A UNIFIED MECHANISM OF BIOLOGICAL METHANE OXIDATION [J].

DALTON, H ;

SMITH, DDS ;

PILKINGTON, SJ .

FEMS MICROBIOLOGY LETTERS, 1990, 87 (3-4) :201-207

[6]

Doi K., 1988, STRUCT BONDING BERLI, V70, P1

[7] HALOALKENE OXIDATION BY THE SOLUBLE METHANE MONOOXYGENASE FROM METHYLOSINUS-TRICHOSPORIUM OB3B - MECHANISTIC AND ENVIRONMENTAL IMPLICATIONS [J].

FOX, BG ;

BORNEMAN, JG ;

WACKETT, LP ;

LIPSCOMB, JD .

BIOCHEMISTRY, 1990, 29 (27) :6419-6427

[8]

FOX BG, 1989, J BIOL CHEM, V264, P10023

[9]

GREEN J, 1989, J BIOL CHEM, V264, P17698

[10]

GREEN J, 1985, J BIOL CHEM, V260, P5795

← 1 2 →