(SO2)-S-32-O-16 - A REFINED ANALYSIS OF THE 3-NU(3) BAND AND DETERMINATION OF EQUILIBRIUM ROTATIONAL-CONSTANTS

被引：46

作者：

FLAUD, JM ^{[1
]}

LAFFERTY, WJ ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,DIV MOLEC PHYS,GAITHERSBURG,MD 20899

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 161卷 / 02期

关键词：

D O I：

10.1006/jmsp.1993.1245

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The spectrum of the 3ν3 overtone band of 32S16O2 has been refitted using a Hamiltonian matrix treatment which includes a Fermi-like interaction term between the (003) and (131) states. As a result, the fitting constants obtained for the higher-order terms now have values consistent with those of the ground state. The rotational constants of a number of vibrational states have been fitted to obtain equilibrium rotational constants and a set of rotation-vibration interaction constants. An improved equilibrium structure has also been obtained. © 1993 Academic Press, Inc.

引用

页码：396 / 402

页数：7

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