HIGH ELECTROCATALYTIC ACTIVITY OF RRSS-[NI(II)HTIM](CLO4)(2) AND [NI(II)DMC](CLO4)(2) FOR CARBON-DIOXIDE REDUCTION (HTIM=2,3,9,10-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE, DMC=C-MESO-5,12-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE)

被引：83

作者：

FUJITA, E ^{[1
]}

HAFF, J ^{[1
]}

SANZENBACHER, R ^{[1
]}

ELIAS, H ^{[1
]}

机构：

[1] TH DARMSTADT,EDUARD ZINTL INST ANORGAN CHEM,D-64289 DARMSTADT,GERMANY

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 21期

关键词：

D O I：

10.1021/ic00099a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrocatalytic activity in aqueous solution and the CO2 binding in acetonitrile were studied for NiDMC(ClO4)(2) and isomerically pure RRSS- and RSSR-NiHTIM-(ClO4)(2). Cyclic voltammograms and bulk electrolyses indicate that RRSS-NiHTIM(2+) and NiDMC(2+) are better catalysts than Ni(cyclam)2+. The CO2 binding constants of the two complexes are estimated to be 4 +/- 2 M(-1) in CH3CN.

引用

页码：4627 / 4628

页数：2

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