The nanostructures of Sm-Co on Cr thin films prepared by de magnetron sputtering were investigated by high resolution transmission electron microscopy (HRTEM) and diffraction techniques, HRTEM micrographs show that the crystallites in the Sm-Co films, as revealed by the lattice fringes, are distributed discontinuously in the matrix. The matrix is amorphous as indicated by microdiffraction study. The size of the crystallites is in the range of 2 similar to 5 nanometers. The volume fraction of the crystallites in the film decreases from 91% to 54% as the argon pressure is increased from 5 mTorr to 30 mTorr, Micrographs recorded in bright field transmission electron microscope (TEM) with a defocus of a few micrometers reveal grain-like structures of about 25 nm in some but dot all films. This grain-structure is found to be inherited from the Cr underlayer.