Mutual isomerization of eta(1)-allenyl and eta(1)-propargyl complexes of platinum via a five-coordinate eta(3)-allenyl/propargyl intermediate

被引：34

作者：

Ogoshi, S

Fukunishi, Y

Tsutsumi, K

Kurosawa, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible spontaneous isomerization between eta(1)-allenyl and eta(1)-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate eta(3)-allenyl/propargyl intermediate.

引用

页码：2485 / 2486

页数：2

共 16 条

[1] INTERCONVERSION OF ETA(1)-PROPARGYL, ETA(1)-ALLENYL, AND ETA(3)-PROPARGYL ALLENYL LIGANDS ON PLATINUM - SYNTHESIS, STRUCTURE, AND REACTIVITY OF [(PH3P)2PT(ETA(3)-CH2CCPH)]O3SCF3 [J].

BLOSSER, PW ;

SCHIMPFF, DG ;

GALLUCCI, JC ;

WOJCICKI, A .

ORGANOMETALLICS, 1993, 12 (06) :1993-1995

[2] INTERMOLECULAR COUPLING OF THE ALLENYL LIGAND ON TUNGSTEN TO FORM HEXA-1,5-DIENE AIDED BY TRIOSMIUM CLUSTERS [J].

CHEN, MC ;

KENG, RS ;

LIN, YC ;

WANG, Y ;

CHENG, MC ;

LEE, GH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (17) :1138-1140

[3]

COLLMAN JP, 1987, PRINCIPLES APPL ORGA, P242

[4]

COLLMAN JP, 1969, INORG CHEM, V8, P2754

[5]

COTTON FA, 1988, ADV INORG CHEM RAD, P1300

[6]

Doherty S, 1995, ADV ORGANOMET CHEM, V37, P39, DOI 10.1016/S0065-3055(08)60598-5

[7] SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME (OMICRON-ALLENYL)PALLADIUM(II) AND (OMICRON-PROP-2-YNYL)PALLADIUM(II) COMPLEXES [J].

ELSEVIER, CJ ;

KLEIJN, H ;

BOERSMA, J ;

VERMEER, P .

ORGANOMETALLICS, 1986, 5 (04) :716-720

[8] A VERSATILE ROUTE TO THE BETA-SUBSTITUTED PI-ALLYL COMPLEXES VIA ADDITION TO A CATIONIC ETA(3)-PROPARGYL COMPLEX OF PLATINUM [J].

HUANG, TM ;

CHEN, JT ;

LEE, GH ;

WANG, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) :1170-1171

[9] PREPARATION AND CHEMICAL REACTIVITIES OF THE TUNGSTEN ALLENYL COMPLEX CPW(CO)3CH=C=CH2 [J].

KENG, RS ;

LIN, YC .

ORGANOMETALLICS, 1990, 9 (01) :289-291

[10]

MINGOS DMP, 1982, COMPREHENSIVE ORGANO, V3, P60

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