PHOTOELECTRON-SPECTRA OF CYCLOPOLYSILANES

被引：8

作者：

JANOSCHEK, R

HENGGE, E

STUGER, H

NYULASZI, L

机构：

[1] TECH UNIV BUDAPEST,INST ANORGAN CHEM,H-1521 BUDAPEST,HUNGARY

[2] GRAZ TECH UNIV,INST ANORGAN CHEM,A-8010 GRAZ,AUSTRIA

来源：

MONATSHEFTE FUR CHEMIE | 1991年 / 122卷 / 1-2期

关键词：

ABINITIO CALCULATIONS; CYCLOPOLYSILANES; PE-SPECTRA;

D O I：

10.1007/BF00815160

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

He (I) PE spectra of cyclopentasilane and cyclohexasilane show excellent agreement with STO-3 G+ ab initio calculations. The HOMO in both compounds is of sigma (SiSi) 3 p character. First IP's appear at 9.4 and 9.6 eV respectively.

引用

页码：31 / 34

页数：4

共 11 条

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