ANOTHER SYNTHESIS OF 1,3-DIPHOSPHOLYL ANIONS AND THEIR USE FOR THE PREPARATION OF 1,1',3,3'-TETRAPHOSPHAFERROCENES

被引：11

作者：

MAIGROT, N ^{[1
]}

SIERRA, ML ^{[1
]}

CHARRIER, C ^{[1
]}

RICARD, L ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,CHIM PHOSPHORE & METAUX TRANSIT LAB,CNRS,UM 13,F-91128 PALAISEAU,FRANCE

来源：

POLYHEDRON | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)83314-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of 1,3-diphospholyl anions has been obtained from 1,3-diphenyl-1,3-diphosphol-4-enes via the metallation of the P-CH2-P unit by n-butyllithium followed by the cleavage of the two P-Ph bonds by lithium in THF. These anions have been allowed to react with the bis-(eta-6-p-xylene)iron dication to prepare novel 1,1',3,3'-tetraphosphaferrocenes which have been characterized by X-ray crystal structure analysis.

引用

页码：601 / 606

页数：6

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