REGIOSELECTIVE AND STEREOSELECTIVE HYDROBORATIONS OF CHIRAL ALLYL AMINES - SYNTHESIS OF AMINO-ALCOHOLS

被引：27

作者：

SIBI, MP

LI, BQ

机构：

[1] Department of Chemistry, North Dakota State University Fargo

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 29期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)74666-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral allyl amines with the carbon-carbon double bond at an internal position undergo regio- and stereocontrolled hydroborations to provide 1,2-amino alcohols in good yields. The precursor olefins are readily available from a nucleophilic alaninol synthon prepared from serine.

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页码：4115 / 4118

页数：4

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