ORGANOMETALLIC SONOCHEMISTRY - SUCCESSES, PROBLEMS AND BY-PRODUCTS

被引：21

作者：

LUCHE, JL

机构：

[1] Univ Scientifique et Medicale de, Grenoble, St. Martin d'Heres, Fr, Univ Scientifique et Medicale de Grenoble, St. Martin d'Heres, Fr

来源：

ULTRASONICS | 1987年 / 25卷 / 01期

关键词：

ORGANOMETALLICS - Ultrasonic Effects;

D O I：

10.1016/0041-624X(87)90010-2

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

This review summarizes work undertaken in the area of organometallic sonochemistry. Organolithium and organozinc reactions promoted by ultrasonic waves offer synthetic advantages over the classical methods with regard to the selectivity, yields and rates. Tentative interpretations of the ultrasonic effects on such reactive systems are discussed. New trends in organometallic chemistry resulting from the sonochemical studies have become apparent, especially new reactions occurring in aqueous media.

引用

页码：40 / 44

页数：5

共 12 条

[1]

BARBOZA JD, 1985, J ORG CHEM, V50, P5761

[2]

EINHORN C, UNPUB

[3] ULTRASOUND IN ORGANIC-SYNTHESIS .9. FURTHER RESULTS FOR THE BOUVEAULT REACTION [J].

EINHORN, J ;

LUCHE, JL .

TETRAHEDRON LETTERS, 1986, 27 (16) :1791-1792

[4] ULTRASOUNDS IN ORGANIC SYNTHESES .1. EFFECT ON THE FORMATION OF LITHIUM ORGANOMETALLIC REAGENTS [J].

LUCHE, JL ;

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[5] ULTRASOUND IN ORGANIC-SYNTHESIS .4. A SIMPLIFIED PREPARATION OF DIARYLZINC REAGENTS AND THEIR CONJUGATE ADDITION TO ALPHA-ENONES [J].

LUCHE, JL ;

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[6] ULTRASOUND IN ORGANIC-SYNTHESIS .5. PREPARATION AND SOME REACTIONS OF COLLOIDAL POTASSIUM [J].

LUCHE, JL ;

PETRIER, C ;

DUPUY, C .

TETRAHEDRON LETTERS, 1984, 25 (07) :753-756

[7]

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[9] SELECTIVE TIN AND ZINC MEDIATED ALLYLATIONS OF CARBONYL-COMPOUNDS IN AQUEOUS-MEDIA [J].

PETRIER, C ;

EINHORN, J ;

LUCHE, JL .

TETRAHEDRON LETTERS, 1985, 26 (11) :1449-1452

[10] CONJUGATE ADDITIONS TO ALPHA, BETA-UNSATURATED CARBONYL-COMPOUNDS IN AQUEOUS-MEDIA [J].

PETRIER, C ;

DUPUY, C ;

LUCHE, JL .

TETRAHEDRON LETTERS, 1986, 27 (27) :3149-3152

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