(NBU4)[SN(PT(MU-CL)(C6F5)2)3], AN UNUSUAL CLUSTER WITH 3 PT(II)-]SN(II) BONDS

被引：29

作者：

USON, R

FORNIES, J

TOMAS, M

USON, I

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza, Zaragoza

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A puckered six-membered Pt3Cl3 ring, which coordinates a ''naked'' Sn (II) center via its basic Pt centers characterizes the cluster core (picture on the right) of the title compound. Not only the Pt-Sn interactions but also short contacts between Sn (II) and the omicron-F atoms of the C6F5-substituents on the platinum contribute to the stabilization of this unusual complex anion.

引用

页码：1449 / 1450

页数：2

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