LITHIATION OF 2,6,6-TRIMETHYL-1-[2-(1,4-DIOXENYL)]-1-CYCLOHEXENE - AN UNEXPECTED DIOXENE RING-CLEAVAGE

被引：5

作者：

BLANCHOT, V

HANNA, I

机构：

[1] Laboratoire de Svnthese Organiaue, D.C.S.O.

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 04期

关键词：

D O I：

10.1080/00397919108016784

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metalation of the title compound 1 with strong lithiating agents leads to ring-opened products. Conditions for regioselective deprotonation affording either alpha,beta-unsaturated ketone 6 or allenic product 9 are described.

引用

页码：563 / 568

页数：6

共 6 条

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