REACTION OF SUPPORTED FLUORIDE-ION WITH GASEOUS SULFUR MUSTARD

被引：11

作者：

BELLAMY, AJ

机构：

[1] Chemical Systems Group, School of Mechanical, Materials and Civil Engineering, Royal Military College of Science, Swindon

来源：

REACTIVE POLYMERS | 1994年 / 23卷 / 2-3期

关键词：

SUPPORTED REAGENT; SULFUR MUSTARD; DECONTAMINATION;

D O I：

10.1016/0923-1137(94)90007-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The behaviour of supported fluoride ion when treated with gaseous sulphur mustard, (ClCH2CH2)(2)S, has been studied. Amberlyst A-26 F- was found to have a large capacity for reaction (1.5 mmol S-mustard/g resin), the only observed organic product being divinyl sulphide. Fluoride ion on other support materials showed much lower reaction capacity.

引用

页码：101 / 106

页数：6

共 6 条

[1] ANIONIC ACTIVATION IN POLYMER-SUPPORTED REACTIONS .2. STEREOCHEMICAL STUDIES ON THE INTRODUCTION OF FLUORINE AT CHIRAL CENTERS AND IN BIOLOGICALLY SIGNIFICANT MOLECULES [J].

COLONNA, S ;

RE, A ;

GELBARD, G ;

CESAROTTI, E .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (09) :2248-2252

[2] NUCLEOPHILIC FLUORINE DISPLACEMENT-REACTIONS - A COMPARISON OF REACTIVITIES OF POLYMER-SUPPORTED FLUORIDE AND ACID FLUORIDES P+F-, NHF (N = 0-2) [J].

COUSSEAU, J ;

ALBERT, P .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (22) :5380-5383

[3]

DAVIS GT, 1984, Patent No. 4449005

[4]

HODGE P, 1980, POLYM SUPPORTED REAC, P85

[5]

STAMULIS A, 1960, NRL5426 US NAV RES L

[6] DECONTAMINATION OF CHEMICAL WARFARE AGENTS [J].

YANG, YC ;

BAKER, JA ;

WARD, JR .

CHEMICAL REVIEWS, 1992, 92 (08) :1729-1743

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