Specific heat measurements show, for LMCO [M = B(Ba), S(Sr); x = 0.09, 0.12, 0.15], hysteresis and anomalous behavior in the 85-125K region and, for LBCO(0.12) and LSCO(0.09), similar magnetic field-dependent anomalies near 70K. Neutron and x-ray studies by others have shown the existence of an orthorhombic-tetragonal transition for LBCO near 70K but gave no indication of structural transitions in the other cases. The occurrence of transitions, and their x-dependence, in these materials is of interest for the possibility of its connection with the x-dependence of superconducting properties including the isotope effect.