PREPARATION AND PROPERTIES OF HIGHLY ELECTRON-ACCEPTING POLY(PYRIMIDINE-2,5-DIYL)

被引：93

作者：

KANBARA, T

KUSHIDA, T

SAITO, N

KUWAJIMA, I

KUBOTA, K

YAMAMOTO, T

机构：

[1] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, 4259 NAGATSUTA, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

[2] TOKYO INST TECHNOL, FAC SCI, DEPT CHEM, MEGURO KU, TOKYO 152, JAPAN

[3] GUNMA UNIV, FAC ENGN, KIRYU 376, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 04期

关键词：

D O I：

10.1246/cl.1992.583

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2,5-dibromopyrimidine with a zero-valent nickel complex affords poly(pyrimidine-2,5-diyl). This new polymer is easily converted into electrical conducting materials by chemical and electrochemical reductions, the latter reduction occurring at the highest potential (-1.75 V vs. Ag/Ag+) among reported pi-conjugated polymers.

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页码：583 / 586

页数：4

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