A STUDY BY IN-SITU FTIR SPECTROSCOPY OF THE DECOMPOSITION OF PRECURSORS FOR THE MOCVD OF HIGH-TEMPERATURE SUPERCONDUCTORS

被引：20

作者：

KOVALGIN, AY ^{[1
]}

CHABERTROCABOIS, F ^{[1
]}

HITCHMAN, ML ^{[1
]}

SHAMLIAN, SH ^{[1
]}

ALEXANDROV, SE ^{[1
]}

机构：

[1] ST PETERSBURG STATE TECH UNIV,DEPT ELECTR MAT TECHNOL,ST PETERSBURG 195251,RUSSIA

来源：

JOURNAL DE PHYSIQUE IV | 1995年 / 5卷 / C5期

关键词：

D O I：

10.1051/jphyscol:1995542

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

In this paper we report on a study by FTIR spectroscopy of the gas phase thermal decomposition of [Y(TMHD)(3)], [Cu(TMHD)(2)] and [Ba(TDFND)(2).tetraglyme] under a total pressure of 10 Torr, for a temperature range 200 - 650 degrees C, and in the absence and presence of oxygen. The variation of the decomposition characteristics for each of the complexes as a function of temperature, and as shown by changes in the absorption coefficients, are related to the molecular structures.

引用

页码：357 / 364

页数：8

共 12 条

[1] MASS-SPECTROMETRIC STUDY OF THERMAL-STABILITY OF COPPER(II) BIS(DIPIVALOYLMETHANATE) VAPOR [J].

BYKOV, AF ;

SEMYANNIKOV, PP ;

IGUMENOV, IK .

JOURNAL OF THERMAL ANALYSIS, 1992, 38 (06) :1463-1475

[2] MASS-SPECTROMETRIC STUDY OF GAS-PHASE THERMAL-STABILITY OF YTTRIUM(III) TRIS(DIPIVALOYLMETHANATE) [J].

BYKOV, AF ;

SEMYANNIKOV, PP ;

IGUMENOV, IK .

JOURNAL OF THERMAL ANALYSIS, 1992, 38 (06) :1477-1486

[3] MECHANISTIC STUDIES OF COPPER THIN-FILM GROWTH FROM CU(I) AND CU(II) BETA-DIKETONATES [J].

GIROLAMI, GS ;

JEFFRIES, PM ;

DUBOIS, LH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) :1015-1024

[4]

Greenwood N. N., 1984, CHEM ELEMENTS, P1497

[5] REPRODUCIBLE MOCVD OF BARIUM FLUORIDE - STUDIES OF THE EFFECT OF THE DEGREE OF PRECURSOR CRYSTALLINITY AND PURITY [J].

HITCHMAN, ML ;

SHAMLIAN, SH ;

GILLILAND, DD ;

COLEHAMILTON, DJ ;

NASH, JAP ;

THOMPSON, SC ;

COOK, SL .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (01) :47-52

[6]

HITCHMAN ML, 1990, I PHYS C SER, V111, P305

[7]

REES WS, 1992, MATER RES SOC S P, P141

[8] METAL-ORGANIC CHEMICAL-VAPOR-DEPOSITION OF YBCO USING A NEW, STABLE AND VOLATILE BARIUM PRECURSOR [J].

SHAMLIAN, SH ;

HITCHMAN, ML ;

COOK, SL ;

RICHARDS, BC .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (01) :81-85

[9]

THOMPSON SC, 1992, ADV MATER OPT ELECTR, V1, P81

[10]

TIMMER K, 1992, INORG CHIM ACTA, V190, P109

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