EXCESS-ENTHALPIES OF MIXTURES CONTAINING NORMAL-HEPTANE, METHANOL AND METHYL TERT-BUTYL ETHER (MTBE)

被引：59

作者：

TUSELLANGER, E

ALONSO, JMG

OLFOS, MAV

LICHTENTHALER, RN

机构：

[1] UNIV HEIDELBERG,INST PHYS CHEM,NEUENHEIMER FELD 253,W-6900 HEIDELBERG,GERMANY

[2] UNIV VALLADOLID,ESCUELA TECR SUPER INGN,E-47011 VALLADOLID,SPAIN

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1991年 / 20卷 / 01期

关键词：

BLENDING AGENT; ALCOHOL + ALKANE MIXTURE; MTBE; QUASIISOTHERMAL FLOW CALORIMETER; MOLAR EXCESS ENTHALPY; NRTL EQUATION;

D O I：

10.1007/BF00651647

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molar excess enthalpies H(E) have been measured for the binary mixtures MTBE + methanol, MTBE + n-heptane and methanol + n-heptane using a quasi-isothermal flow calorimeter. The measurements have been performed at atmospheric pressure and at 25 and 40-degrees-C for all the mixtures and for MTBE + methanol also at 50-degrees-C. The experimental results for MTBE methanol and MTBE + n-heptane are compared with those calculated using the NRTL equation.

引用

页码：153 / 163

页数：11

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