THE OXYGENATION OF FLAVONOL BY COPPER(I) AND COPPER(II) FLAVONOLATE COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(FLAVONOLATO)COPPER(II)

被引：55

作者：

BALOGHHERGOVICH, E

SPEIER, G

ARGAY, G

机构：

[1] UNIV VESZPREM, DEPT ORGAN CHEM, H-8201 VESZPREM, HUNGARY

[2] HUNGARIAN ACAD SCI, CENT RES INST CHEM, H-1525 BUDAPEST, HUNGARY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 08期

关键词：

D O I：

10.1039/c39910000551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flavonol is oxygenated to the corresponding depside catalysed by Cu(I) and Cu(II) flavonolate complexes; X-ray structure determination of bis(flavonolato)copper(II).2CHCl3 shows that the two flavonolate ligands are coordinated to Cu(II) through their 3-hydroxy and 4-carbonyl groups to result in a square planar geometry around copper(II).

引用

页码：551 / 552

页数：2

共 15 条

[1] MAGNETISM ELECTRONIC SPECTRA AND STRUCTURE OF TRANSITION METAL ALKOXIDES .I. METHOXIDES AND ETHOXIDES OF CHROMIUM(2) MANGANESE(2) IRON(2) COBALT(2) NICKEL(2) COPPER(2) TITANIUM(3) CHROMIUM(3) AND IRON(3) [J].